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1
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2
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- Particles of matter are ALWAYS in motion
- Volume of individual particles is » zero.
- Collisions of particles with container walls cause pressure exerted by gas.
- Particles exert no forces on each other.
- Average kinetic energy µ Kelvin
temperature of a gas.
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3
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- Kelvin temperature is an index of the random motions of gas particles
(higher T means greater motion.)
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4
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5
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6
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7
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8
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- Is caused by the collisions of molecules with the walls of a container
- is equal to force/unit area
- SI units = Newton/meter2 = 1 Pascal (Pa)
- 1 standard atmosphere = 101.3 kPa
- 1 standard atmosphere = 1 atm =
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9
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10
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- Gases expand to fill their containers
- Gases are fluid – they flow
- Gases have low density
- 1/1000 the density of the equivalent liquid or solid
- Gases are compressible
- Gases effuse and diffuse
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11
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- P = 1 atmosphere, 760 torr, 101.3 kPa
- T = 0°C, 273 Kelvins
- The molar volume of an ideal
gas is 22.42 liters at STP
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12
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13
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14
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15
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- The volume of a gas is directly proportional to temperature, and
extrapolates to zero at zero Kelvin.
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16
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17
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18
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19
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20
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21
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- PV = nRT
- P = pressure in atm
- V = volume in liters
- n = moles
- R = proportionality constant
- T = temperature in Kelvins
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22
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23
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24
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25
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26
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27
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28
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- For a mixture of gases in a container,
- PTotal = P1 + P2 + P3
+ . . .
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29
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30
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- Effusion: describes the passage
of gas into an evacuated chamber.
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31
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